PPE is part of our political landscape these days, so here is a short article from wikipedia about the history of ppe.
https://en.wikipedia.org/wiki/Personal_protective_equipment
https://en.wikipedia.org/wiki/Personal_protective_equipment
Early PPE such as body armor, boots and gloves focused on protecting the wearer's body from physical injury. The plague doctors of sixteenth-century Europe also wore protective uniforms consisting of a full-length gown, helmet, glass eye coverings, gloves and boots (see Plague doctor costume) to prevent contagion when dealing with plague victims. These were made of thick material which was then covered in wax to make it water-resistant. A mask with a beak-like structure which was filled with pleasant-smelling flowers, herbs and spices to prevent the spread of miasma, the prescientific belief of bad smells which spread disease through the air.[2] In more recent years, scientific personal protective equipment is generally believed to have begun with the cloth facemasks promoted by Wu Lien-teh in the 1910–11 Manchurian pneumonic plague outbreak, although many Western medics doubted the efficacy of facemasks in preventing the spread of disease.