Trust me, you can duplicate those conditions in the laboratory and produce obsidian. You just need to mix the proper ratios of Si, Al, Ca, Na, K and iron. It will melt and react at around the same temperature as glass, a little lower actually and the Iron acts as a very powerful flux will have a significantly lower melt viscosity. Then allow enough residence time for off gassing to complete to eliminate bubbles the cool it quickly to below nucleation temperature. Then anneal for a set amount of time below nucleation temp to eliminate stress risers in the materials matrix then allow to cool and you’ll have a workable piece of obsidian.