Because there isn't the tiniest, slightest piece of evidence that biological life can exist independently of carbon and water.
After four billion years of Earth history there was plenty of time and opportunities for silicon based or iron based biology to develop, but they never did.
Misconceptions of Science: Is Silicon-based Life Possible?
Is Silicon-Based Life Possible?
Why do people think that silicon-based life may be possible? The reason is simple. Silicon is below carbon on the periodic table and silicon can also make four bonds. So, it stands to reason, you could just as easily make complicated molecules with silicon. That makes perfect sense, except it’s not true. Why is that?
So, let’s contrast silicon and carbon. They can both form four bonds. On Earth, silicon is far, far, far more prevalent than carbon. Basically, silicon is found in sand and rock. In the Earth’s crust, silicon makes up 28%. Carbon, in contrast, is about 1,000 times less common. Yet carbon makes up life, while silicon doesn’t. If silicon were a contender, the fact that it is so common would give it a huge advantage.
So why does silicon fall short? Well, to begin with, when carbon makes four atomic bonds with all of its neighbors, the bonds tend to be of the same strength. In silicon, the first bond is much stronger than the others, which means the first bond is far more stable than the others.
It’s because the first bond is formed when the electrons from each atom reach directly to the other atom in a metaphorical handshake. The other bonds are formed from electrons that are further away and they effectively don’t get as good a grip.
Another thing is that when carbon connects with other chemicals common in organic molecules, the bonds are of similar strength. Carbon–carbon, carbon–oxygen, carbon–hydrogen, and carbon–nitrogen are all pretty similar. That means that, from an energy point of view, it is pretty easy to swap out atoms, which is the physicist’s way of saying that chemical reactions occur.
However, the silicon–oxygen bond is much stronger than say silicon–hydrogen, or silicon–carbon, or even silicon–silicon. That means that once silicon interacts with oxygen, it’s very hard to break them apart. This makes the ease and versatility of silicon chemical interactions far lower than the ones involving carbon.
And, about that silicon–oxygen bond compared to the carbon–oxygen one. When you breathe, you take in oxygen and breathe out carbon dioxide, which is given by the chemical formula CO2. The corresponding silicon molecule is SiO2 or silicon dioxide. The more common word for that chemical compound is ‘rock’.
Thus, a silicon-based creature using oxygen as part of its energy cycle would be breathing out sand. This isn’t a new realization. In 1934, science fiction author Stanley Weinbaum wrote a story in the pulp fiction magazine called Wonder Stories of an expedition to Mars. The astronaut encountered a life form that was gray, with one arm and a mouth that extruded bricks. He realized that the bricks were the product of the creature’s respiration.
So, while a simple understanding of the chemistry of carbon and silicon suggests that silicon-based life is possible, if you dig a bit deeper, it seems that silicon-based life isn’t really all that likely.
https://www.wondriumdaily.com/misconceptions-of-science-is-silicon-based-life-possible/